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132.Transition-Metal-Free Direct gem-Difluoroallylation of β,γ-Unsaturated α-Amino Nitrile Derived Lithium Reagents
Ming-Chen Huang, Hai-Yang Zhao, and Xingang Zhang*
Chin. J. Org. Chem. 2026, 46, 3676-3687.
(Invited paper)
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131.Trifluoroallyl Sulfonium Salts:Reagents for Highly Regioselective Trifluoroallylation
Yuan-Zhan Han, Zhi-Yuan Yang, Hai-Yang Zhao, Qiao-Qiao Min,* and Xingang Zhang*
Org.Lett. 2026, DOI: 10.1021/acs.orglett.6c03732
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130.Diastereoselective Synthesis of Difluoromethylene—Bridged Cyclopropane-Cyclobutanes from 2-(Difluoromethylene)-cyclobutyl Sulfonium Salt and Cyclopropenes
Shi-Chang Gao, Xiao-Tian Feng, Hai-Yang Zhao, and Xingang Zhang*
Chin. J. Chem. 2026, 44, 2323—2328.
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129.Controllable Difluorocarbene Elongation via Copper Catalysis
Ming-Chen Huang, Shasha Geng, Xin Zeng, Hai-Yang Zhao, and Xingang Zhang*
J. Am. Chem. Soc. 2026 , 148, 17835-17846.
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128.Facile access to difluoromethylene-linked strained aliphatic rings from 2-(difluoromethylene)cyclobutyl sulfonium salts (CB-DFAS) and [1.1.1]propellane
Song-Yu Zhang, Yuan-Zhan Han, Xiao-Tian Feng, Hai-Yang Zhao and Xingang Zhang*
Chem. Commun. 2026, 62, 7953-7956.
(Invited paper)
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127.Unlocking Difluorocarbene as a Versatile Precursor toFluorocarbon Anions and Radicals via Palladium Catalysis
Shi-Ping Sun, Xingang Zhang*
Synlett 2026. DOI: 10.1055/a-2803-0545
(invitated Synpacts)
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126.Kinetic Influence of Electrophile-Alkene Exchange ofNickel-Alkene Complexes in Oxidative Addition
Yun-Cheng Luo, Yi-Hao Xu, and Xingang Zhang*
Chin. J. Chem. 2026, 44, 1073-1082.
(Cover Story)
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125.Unlocking Difluorocarbene as a Fluorocarbanion and a Fluorocarbon Radical Precursor for Sequential Catalytic Coupling
Shi-Ping Sun, Tong Mu, Xue-Ying Zhang, Xia-Ping Fu, Hai-Yang Zhao, Yanxia Zhang, Xiao-Song Xue, and Xingang Zhang*
J. Am. Chem. Soc. 2025, 147, 38897-38906.
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124.Difluoromethylene Cyclobutyl Sulfonium Salts: Versatile Reagents
for Chemodivergent Synthesis of Difluoroalkylated Cyclobutenes
and Cyclobutanes
Xiao-Tian Feng, Qiao-Qiao Min, Song-Yu Zhang, Hai-Yang Zhao, and Xingang Zhang*
Chemical Science, 2025, 16, 16552–16558.
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123.A Bench-Stable Monofluoroallylsulfonium Salt for Highly Regioselective Monofluoroallylation
Ming-Xing Qu, Jian Zhang, Hai-Yang Zhao, and Xingang Zhang*
Eur. J. Org. Chem. 2025, 00, e202500625.
(invited paper for European Journal of Organic Chemistry)
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